Sinister Six appears in 23 issues in this volume.
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Issue #334
Secrets, Puzzles and Little Fears
July 1, 1990
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Issue #335
Shocks
July 1, 1990
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Issue #336
The Wagers of Sin
August 1, 1990
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Issue #337
Rites and Wrongs
August 1, 1990
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Issue #338
Death From Above
September 1, 1990
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Issue #339
The Killing Cure
September 1, 1990
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Issue #574
Flashbacks
December 1, 2008
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Issue #638
One Moment In Time Chapter One: Something Old
September 1, 2010
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Issue #642
Origin of the Species, Part 1
November 2010
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Issue #643
Origin of the Species, Part 2
November 1, 2010
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Issue #644
Origin of the Species, Part 3
November 1, 2010
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Issue #648
Big Time
January 2011
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Issue #654.1
Flashpoint
April 16, 2011
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Issue #659
Fantastic Voyage, Part 1; Infested, Stage 1: Bug Time; Can't Get The Service, Part 2
June 27, 2011
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Issue #660
Fantastic Voyage, Part 2; Infested, Stage 2: Great Power; Can't Get the Service, Part 3
July 11, 2011
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Issue #676
The Sinister Six in 'Tomorrow the World!'
February 21, 2012
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Issue #681
Horizon, We Have a Problem
May 7, 2012
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Issue #682
Ends of the Earth, Part One: My World On Fire
May 2012
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Issue #683
Ends of the Earth, Part Two: Earth's Mightiest
June 4, 2012
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Issue #684
Ends of the Earth, Part Three: Sand Trap
June 18, 2012
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Issue #685
Ends of the Earth, Part Four: Global Menace
July 2012
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Issue #686
Ends of the Earth, Part Five: From the Ashes of Defeat
July 2012
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Issue #687
Ends of the Earth, Part 6: Everyone Dies
August 13, 2012
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