I can see Rogue winning two ways, but these aren't very likely at all.
1) The Kryptonite card (almost required for any Superman vs. battle). Can she absorb energy from nonliving things? If she can't, there's two possibilities. Absorb the energy from someone that can absorb energy from nonliving things or have someone make living kryptonite and she could then absorb its energy.
2)She could line a lot of people up from least to most powerful, and deck them down the line, working her way up to Superman. (I'd tell her use the battle rankings here, except she'd have to fight Galactus before Spiderman). It'd have to fast, because earlier fight powers would dissipate. This would be a long line, so she'd better drink a couple of liters of Jolt, or somehow absorb Flash.
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