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Anthony Stark is one of the most brilliant minds of his age. He owns and runs his own corporation also owning advanced technological suits.
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Tony Stark's older brother in the Ultimate Universe, Gregory Stark is just as, if not more, smarter than his baby brother. He is now deceased.
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Due to cosmic rays, Reed Richards was transformed into the elastic Mister Fantastic, but even before then, Reed had the brain of a super computer.
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A beautiful young woman with the brains to match, Susan Storm-Richards is a mother, wife, and incredible superhero.
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Reed and Sue's firstborn, Franklin is mainly known for his omega-level mutant powers, but he is also a genius like his father.
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Sue and Reed's youngest child, Valeria the spitting intellectual image of her parents.
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Bruce Wayne is a very rich man, but it takes nothing away from his intelligence. All those increasingly cool bat-toys don't make themselves. Also, you kinda need to be smart to be considered, oh, ya know, World's Greatest Detective.
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Tim Drake is the third Robin to accompany Batman, and by far, he's the one who is more similar to Bruce than his brothers. He's very intelligent and a great detective as his mentor.
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Oliver Queen is the man in power at Queen Industries, as well as the manufacturer of his arsenal of special arrows as the Green Arrow.
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Any man whose held the mantle of the Blue Beetle has been intellectual and a gear head.
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Henry Pym is another one of Marvel's brainiacs that people love and know. I mean he created Pym Particles and is the Scientist Supreme, after all.
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He served as Sorceror Supreme for the better part of his life so apparently he has to have some intelligence if he's never accidentally turned the world inside out.
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Intellectual rival of Reed Richards since they first met and the ruler of Latveria, tell me he isn't a smart @$$?
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A man that can walk along the surface of the sun, travel to universe faster than we can blink, even break something down to the very elements it came from must be intelligent off the scale
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The World's Smartest Man. Need I say more?
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Whether you truly believe he's crazy or not, if you are given the title of Batman's Deadliest Foe, you can't just be able to kill, you gotta be smart.
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