I'll go with Cap, considering the damage he already does with his shield; it would be insane with Mjolnir. The only thing that gives a doubt is if Cap launch a lightning strike on Iron Man, doesn't his armor get powered up? Remember in Avengers 1 when Thor strikes Tony, Jarvis said "power up to 400%". Now, considering Cap can't use lightning for that specific reason, single blows from Mjolnir are super powerful yes, but minus the lightning, his powers are downgraded so he is less powerful against Iron Man.
As for the bonus round, it can go either way I think.
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