The Power Gem: With Spiderman's stealth ability and the suit of armor from Tony, upgraded by T'Challa Spidey could sneak into Marvel's Atlantis, and steal the gem. Secondly, when does Thanos really need a reason to do anything? For Thanos this could be sheer amusement. Also with the possible colliding of two universes Spiderman's quest could possibly destroy both universes given the proper scenario, and Thanos would find this enjoyable and help Spidey. So it's possible for Spiderman to make a selfish deal with Mephisto to save Aunt May, but not with Thanos to possibly save the universe. (A good writer could, and would create the possible scenario) Here is a scenario I made up on my own: Access (The character created and owned by both Marvel and Dc) is in the DC universe when he suddenly falls ill. He collapses on he street and is rushed to a hospital in Metropolis. There he is announced as a Jon Doe. He is in a coma, and is having sporadic seizures, little does anyone know this is Darksied's doing. Darksied remembers a gauntlet from another universe and how it appeared to be a power source. He captures Metron and uses his Mobius chair to breach the Source Wall creating a Boom tube into the Marvel Universe. Not able to find the gauntlet he does find the M'Kraan Crystal and takes it. Now all of the Marvel U is in danger of wiped out. Darksied goes thru with some grand plan to use the crystal and is stopped by the JLA. They take the crystal back to the Watchtower. Spiderman is chosen by the Grandmaster to go to the DCU and recover the crystal before all is lost. Why is Spidey chosen? Because he is Marvel's flagship character, and sending the Surfer on this quest with the ability to get help from "Any resource" is unfair. But use a hero that is not that powerful, and it gives you a chance to show his character. But you could even have the JLA take Spidey down after a long drawn out innovative battle, and when questioned by the JLA Spidey reveals his true quest, and now the JLA jump in to save a universe not theirs, and return Spiderman, and the crystal to their rightful places. Oh, and the whole "preventing your brain from getting smashed around in your skull." That is why the suit would be reinforced with Uru. Duh....
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