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Black Widow's first appearance as an Iron Man villain in issue #52 (1964).
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Black Widow officially joins The Avengers in issue #111 (1973)
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Black Widow is a founding member and original leader of The Champions (1975-1978)
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Vol 1 (1999)
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Vol 2 (2001)
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Vol 3 (2004)
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Vol 4 (2010)
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Vol 5 (2014)
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Vol 6 (2016)
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Vol 7 (2019)
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Vol 8 (2020)
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