Madara wins this.
-Madara's not loosing in Taijutsu. A weaker version of him took the full force of all the five steps of the EE and got up after that.
Sasuke's Taijutsu comes nowhere close to Might Guy. Plus Madara is superior physically in every category except speed and has 5 other clones fighting alongside him.
-It took the combined forces of Naruto and Sasuke just to get rid of some of Madara's Meteors and it was mostly Naruto who got rid of them. Madara just easily makes the Meteorites much bigger than before or makes it into one core and if he does that Sasuke without the Bijuu doesn't have the firepower to destroy the Chibaku Tensei.
-Last resort which he won't need is to absord the Infinite Tsukuyomi Chakra.