Mister 104 appears in 23 issues.
The classically green-skinned member of the The Teen Titans, Beast Boy has the power to transform into any creature of any size.
Rita Farr was a Hollywood actress until her career was ruined after being exposed to unusual volcanic gasses while shooting a film in Africa. Rita discovered she had the ability to grow or shrink herself to any size. Shunned and with nowhere else to turn, she accepted an offer from Dr. Niles Caulder (a.k.a. The Chief) and became a member of Doom Patrol.
Larry Trainor was flying an experimental airplane, when it crashed. He soon discovered that his body housed a radioactive being, renamed himself the Negative Man, and joined the Doom Patrol.
Cliff Steele is actually is a cyborg, rather than a robot, and is one of the founding members of Doom Patrol. He is the only member to appear in every incarnation of the team, and has even served as its leader.
The Chief is a wheelchair bound genius who formed the Doom Patrol.
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