Mirko appears in 1 issues.
All For One is All Might's arch enemy, the founder of the League of Villains and the mentor and adopted father of Tomura Shigaraki. He wishes to see All Might suffer and die along with Tomura's success.
Dabi is a villain who joined the League Of Villains in order to fulfill the Hero Killer Stain's Will of cleansing the society of false heroes.
Himiko Toga is a Highschool girl turned villain who went to join the League Of Villains, inspired to do so in order to meet/kill The Hero Killer, Stain and to make life easier for herself so she can live how she wants.
Rikiya Yotsubashi a.k.a Re Destro is the descendant of Destro and the leader of the now defunct Metahuman Liberation Army. He is currently a commander of the Paranormal Liberation Front after his battle with Tomura Shigaraki.
Leader of the former Villain Alliance, who's goal was to kill All Might "The Symbol of Peace". His goal would later change to destroying society as a whole.
A big fan of the Hero Killer: Stain who becomes a member of the League Of Villains after hearing about Stain's connections with the group.
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