Kon appears in 64 issues.
Gin Ichimaru is a rogue Soul Reaper that turns on his allies and joins his friend Sosuke Aizen to try and destroy the Soul Society.
Grand Fisher is a Hollow from the manga/anime Bleach. Later on in the series he becomes an Arrancar.
The blind Soul Reaper who follows the path of with the least amount of suffering.
Sosuke Aizen was the Soul Reaper's 5th Division's captain until him and his allies, Gin Ichimaru and Kaname Tosen try to destroy kill Rukia for the Orb of Distortion.
Ulquiorra is an Arrancar in Sōsuke Aizen's army. He is also the 4th Espada. You can see the leftovers from a hollow mask on the top left side of his head.
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