Batman #63 - The Origin of Killer Moth - The first appearance of Killer Moth.
Batgirl Year One - This serves as an origin story for Batgirl, with Firefly and Killer Moth teaming up as the villains (with Moth not realizing what he's getting in to).
Batman: Shadow of the Bat #7 & Batman: Shadow of the Bat #8 & Batman: Shadow of the Bat #9 - If you want to read all of the major Killer Moth appearances than you should check these issues out. In this, we get a much darker version of Drury Walker who teams up with pre-Long Halloween Calendar Man and Catman.
Underworld Unleashed #1 - This issue features the first appearance of Killer Moth as Charaxes.
Batman #652 - Face the Face, Part 4 of 8 (Face the Face) - This issue features a new, unidentified, Killer Moth (it's best to buy the whole Face the Face series unless you just want the Killer Moth issue and don't care about the storyline).
Red Robin #9 - Collision, Part 1 - This, once again, features the new Killer Moth (who is unidentified) but it's quite an enjoyable read.
Green Arrow #25 - Zero Year: The Prodigal; New Tricks - This features the first appearance of the New 52 version of Killer Moth (who is vastly different from the usual version, although he is still quite an interesting and cool character).
Green Arrow #31 to Green Arrow #34 - Broken (New 52) - Killer Moth plays quite a major role as one of a handful of villains in this series.
All-Star Batman #1 - My Own Worst Enemy Part 1; The Cursed Wheel Part 1 - Killer Moth has a short but sweet appearance in this along with Firefly. This is the first DC Rebirth issue to feature Killer Moth.
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