Tony Stark has designed and built a variety of armors which he uses as Iron Man. Their appearance and capabilities are continually evolving as Tony modifies and upgrades his technology.
You mean the 'One More Day' disaster? That was a) a powered up post 'the Other' Spider-Man that no longer exists and b) the worst written Spider-Man story in history. That should never have happened.
All Iron Man would need to beat Spidey would be a sample of his 'spider-tracer' material. Then just saturate the local atmosphere with a fine mist of the material and spam Spider-Man's Spider Sense.
Punisher pulled off something similar in an issue of "What if..." He managed to kill Spidey by aiming for an explosive detonator that he had disguised as Doctor Octopus. Spider-Man's spider-sense went off, but no more so than if he'd been confronted with the real Doc Ock. By then, it was too late.
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