Gasper Vladi appears in 3 issues.
Asia Argento is a Nun/Sister Issei meet when strolling in town. She is an innocent and caring individual, always thinking of others before herself. She wields the divine sacred gear Twilight Healing which ca heal any injuries. She was excommunicated from the Church when they found out the she can also heal Devils and Fallen Angels.
Irina Shidou is a young woman who appeared with Xenovia, tasked by the Church to retrieve the missing Excalibur s. It is revieled that she is Issei's childhood friend, though he confused her for a boy then.
Irina is a devout Christian, even after the Kokabiel incident and learning that God is dead, she still remain with the Church and serves as Arch Angel Michale's peerage with the rank of Ace of Spades.
Rias Gremory is the primary female protagonist of High School DXD. Born as a pure blooded devil from a prestigious and powerful clan, the Gremory. She is also the sister of Sirzechs Lucifer, the current Overlord.
She is the president of Kuoh Academy's Occult Research Club, most of its members are part of her peerage.
Yuuto Kiba is one of the main characters in High School DXD. He is a second year at Kuoh Academy and popular as one of the best looking men in school. He is part of the Occult Research Club and serves as Rias Gremory's Knight.
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