Lot of people are gonna say Batman and possibly rightfully so but let's not discount Thanos as he was able to obtain the cosmic cube, infinity gauntlet, HOTU etc. Pretty much every goal he sets out to do he accomplishes with his prep skill. He just obviously gets thwarted later.
Thanos. He was able to gather a nigh-omnipotent artifact not once, twice, thrice, but four times. Thanos, at his strongest could challenge the Beyonder. THE FRIGGIN BEYONDER. That's far greater than anything Batman has done with prep.
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