to solve the most difficult math problem you need a good base knowledge. Simply knowing the math in high school and university won't cut it. You need to read thousands of theories, thesis from other mathematician. So Superman is out, no matter how fast your brain is, you can't conjure other thesis out of nothing. Batman and Ironman could do it given time but since this isn't in their field of specialty they would need to find those thesis and research. Lex and Bruce are both scientist, so they have a bigger head start. Bruce is more about science research than Lex so I think Bruce Banner win this.
Lex Luthor has made it 99 problems in when reed richards stops by and just says the answer to the final most difficult problem outloud spoiling the victory
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