To imagine this switch we would have to put the characters in the same situations. The Avengers, in the Kyln, would be completely unarmed. That would mean no armor to Tony or gear to Cap, Widow and Hawkeye. I can see them finding a way to neutralize Banner's Gamma rays, but they definetly couldn't destroy Mjolnir. It's most likely that the nova would lock the hammer in some well guarded place for studies. In that situation, Thor alone could bring it to him and escape the prision with brute force. If we assume they know about the Orb and have the Ravagers help, they could defeat Ronan.
Guardians could keep the Helicarrier in air with some Rocket tech, specially if you remember they won't have to deal with Hulk or Hawkeye. Considering they would have standart gear (wich includes Milano and all their gear) they could destroy the Chitauri. I'm not sure what they'd do about the nuclear missle, but Rocket could find a way.
The abilisk is a pretty easy task for the Avengers. I can't see any of them stealing one of the batteries like Rocket did. Maybe Tony. But if the sovereing go after them, they die (none of them can pilot like Quill or Rocket, assuming that they would have a spaceship to scape) I don't think they would find out how to kill Ego in time, but with this knolegde they would crack his brain via Vision or Thor. But again, I think it would be much harder without Quill distracting Ego, Mantis putting him to sleep (can't say if she would join the avengers, even if we are counting with her help it's still hard for them) or baby Groot using the batteries. Overall, the Avengers lose.
Guardians could easily break Strucker's base. And they wouldn't mess with the scepter, so no Ultron. But if he still is born, he couldn't leave the Avengers tower with the scepter, Rocket or Quill would follow and destroy him. Even if they don't, Ultron couldn't take the Vibranium in South Africa, once Guardians wouldn't have to worry about Hulk, again. And even if he leaves with the vibranium, Guardians could just blow up Ultron's truck in Seoul. And if Ultron still manages to make his sokovia machine, Rocket would revert the antigravitational devices before it leaves the ground. You should also remember they would have Vision anyway if they recover the Cradle. But I think they could erase Ultron with the mind stone, even without Vision.
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