Kingpin used to have a laserbeam cane.
Daredevil's most hated enemy was somewhat more of a Bond villain when he tangoed with Spider-Man. One example of his more cliche villain traits was a cane with a diamond on the top that had a laser beam installed if Fisk needed to defend himself in a scenario where his insane muscles wouldn't be enough.
Lex Luthor was married to an immortal woman.
Lex was married once to Contessa Erica Alexanda Del Portenza. Contessa was an old associate of Lex that had gained control over Lex Corp after Lex had lost it, so he married her in order to get it back. Contessa was an extremely wealthy woman due to being hundreds of years old and having a network of criminal associates and illegal businesses. Contessa and Lex became enemies after she had given birth to their daughter that neither of the parents wanted to share with the other.
Doctor Sivana could break out of jail thanks to math.
And I don't mean it as in he could calculate the best way to somehow escape, I mean that he knows a mathematical formula which, when recited, allowed him to walk through walls and solid objects, making himself almost impossible to imprison or even catch. Long-term use of this technique takes a life-endangering physical toll on the user.
Professor Zoom hates Flash for killing him.
When the Reverse flash traveled to the past to meet Barry Allen, he did so because he was his biggest, most mentally unstable fan. But he miscalculated and arrived shortly after Barry had died and he learned after visiting the Flash Museum that he was dead in this time, killed by his idol. Zoom lost whatever he had left of sanity and decided to avenge himself... which resulted in him creating the situation where he got killed by the Flash.
Doctor Doom has a daughter with Morgan Le Fay.
Doom once traveled to the past and met Morgan Le Fay, one of the greatest sorcerers of all time and the sister to the legendary king Arthur. She tutored him in the dark arts and they even had an affair. One that resulted in a daughter named Caroline Le Fay who is a villain in present time since her mother sent her to the future to be raised by her followers.
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