Now there's been multiple versions of it. Going from the comic books, and the filmography.
Originally it was vibranium but it was transmuted into adamantium (which should mean it has entirely different properties now as a different metal). Then became some sort of composite. Then it only gets messier from there. Then the movies decided to just call it vibranium because of copy right issues.
1) Does it actually absorb kinetic energy, and does it do so normally?
This question annoys me the most as it creates a paradox where the shield simply cannot function. Now the general belief is that it does. The problem it almost never does so constantly, and Steve Rogers is able to overcome this in order to use it as a weapon somehow. We see Captain America being pushed back, or characters overcoming it in order to make Steve Rogers strain himself to hold back their attacks. As well as their attacks reverberating across his body, and causing it to shake. Now here comes the most confusing part of this.
2) If it absorbs kinetic energy how can it be used as a weapon?
In order to do so Steve Rogers would have to be producing more energy that its ever absorbed, and exceeding that amount. Suggesting that Steve Rogers is somehow stronger than the likes of the Hulk, and Thor. Which is positively outlandish. Steve Rogers is not as strong as they are let alone stronger than them.
Now I know most people are going to say "it's a comic book, I don't have to explain anything." Here's the problem the comic books don't explain it either, and they skirt around the issue. By their own logic using it as a weapon should be impossible if it absorbs kinetic energy. Yet, it is used as a weapon by people clearly not strong enough to overcome its kinetic energy absorbing abilities.
Then next explanation is that it is using antarctic vibranium instead. Which doesn't make sense either. As it apparently causes adamantium to melt. Which if the shield was a composite of both it wouldn't work either. Well, unless it was made entirely out of vibranium.
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