Team Cap would win. Wanda neutralizes Vision immediately. Hawkeye uses trick arrows to down Widow. Cap goes after Panther and holds him off while Bucky, Hawkeye, and Falcon take down Spidey. Then they help Cap with Panther. Meanwhile Giant Man takes out War Machine and Iron Man. Neither can bring him down, and eventually he'll hit them. If he has trouble Wanda can help out with TK. As for the ranking:
1. Vision: He's obviously got the most raw power. His phasing makes him nigh impossible to down, and his blasts clearly have more damage output than anyone else on either side. He barely fought in the movie and was still arguably the greatest power presence. While Wanda would beat him, that's due to a specific weakness rather than actual raw power.
2. Ant Man: He's just so versatile. He might be my favorite MCU Character and I don't even like Comic Ant Man. He can shrink and dispatch most foes through stealth and his ability to think on his feet. He can dismantle armors or weapons, and even at ant size he can knock around Spider-Man for a bit. His ants can provide distractions or harm street level opponents. If he goes big he outclasses everyone but Vision in raw power, and has insane durability. That's not even getting into the discs which allow him to bring down higher tier opponents than even Vision if he can tag them, or just mess with the environment around them to throw the opposition off guard.
3. Scarlet Witch: She's also very versatile. She has TP, though she's never actually used it effectively in combat so that's why she's not higher. But even her TK allows her suspend Vision, temporarily contain a pretty high grade explosion, deflect bullets, toss around Spider-Man, and do other generally useful things. She's just clearly closer to street level than the other two, who are solidly mid-high tier live action characters.
4. War Machine: I know Tony seemingly has the better suit, but the movie didn't depict it like that at all. Rhodey seemed far more effective at every turn. He clearly has a much hpbigger Arsenal due to excessive weapinry and HAMMER upgrades. He tanked much more apdamage than Tony without going down, also seems much smarter in combat.
5. Iron Man: He's got more firepower than anyone below him, and the suit gives him better strength and durability.
6. Black Panther: The guys got a bullet proof Vibranium Suit, Claws that can scratch Cap's shield, and agility and speed above anyone else in the movie bar Spider-Man. He's also got skill clearly only matched by Cap himself. Plus he was the best part of probably the second best CBM of all time.
7. Falcon: Man, his gear boost was simply insane. He had dual Boba Fett style rocket launchers, multiple other explosives deployed from the suit, and his wings are clearly highly damage resistant. He can use them almost as a more effective version of Cap's shield, and they offer an instant protective barrier from opponents. His skills also clearly grew as he deflected bullets right and left. Red Wing was awesome as well, allowing him to attack from multiple fronts. I know Spider-Man beat him handily, but he was clearly going easy on Parker as he didn't use half his firepower.
8. Spider-Man: Although Cap beat him, that was largely due to the environment. Objectively, Spidey is more powerful against most opponents. He easily overpowered Winter Soldier, and was the fastest character in the movie. If it weren't for his inexperience he might be a couple spots higher.
9. Captain America: He's clearly the most skilled combatant and his physicals were on par with guys like Spidey and Panther in almost every regard.
10. Winter Soldier: I'd put him barely below Cap. He did overpower him in their first encounter, but Steve was clearly holding back and basically just BFR'd. The shield is also a bug advantage.
11. Hawkeye: He's got great aim and some very impressive trick arrows. Plus he finally got some H2H feats.
12. Black Widow: Just really not that impressive.
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