@assemblesquad:
The only ones I can think of are some werewolves, provided they aren't more experienced ones on the full moon - in which case, they might still overpower Luke. He gets an easy win vs human hunters.
Many of the witches are D caliber, only able to do some basic movement or other sorts of spells - like early TVD Bonnie. Luke would be more than a match to be able to win that. However, there isn't a way he goes up against even a mid-tier or upper tier witch and wins. They will spin him about and throw him across the room in magical telekinesis, or just render him asleep or a number of other spells some witches have done from time to time. Like a magically induced brain aneurysm.... Which has happened, and Luke would have no defense against.
As for vampires - maybe only a very unexperienced young vampire. They make a dumb mistake, luke takes advantage and gets the drop for the critical strike... But I can't see a competent vampire of any age from 10 years to beyond losing (an original, or a Strix 1000 year old vampire is way overkill). Almost all of them will have greater or at worst equal strength to Luke - but what's worse... Luke will be hopelessly outclassed in speed. Remember, only a 150 year old vampire in Damon - sprinted across an entire town in less than 1.5 seconds in what it took for Elana to finish her sentence over the phone with him on. They are hypersonic creatures at a lower vampire age, Luke has no chance if he doesn't have a massive durability and strength advantage - which he definitely does not, not even close. And this is without things like compulsion.
What about some of the other weird oddities?
I think the succubus sent after some of the originals in the TVD days would beat Luke. I think Silas or some of the other mind controlling oddities stomp. The Devil definitely stomps. The Sirens wreck. The heretics completely outclass him - but then again, most competent witches or vampires did anyway, and this is just a merger of those concepts.
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