In these battles we always assume the characters are fighting at their best, so Starfire wins
We assume they're fighting at their best, but in round 1 its at their best in character. Tony was very smart, but very arrogant and could get caught off guard easily by how deceptively powerful Starfire is. However if he doesn't get immediately koed and recognizes the threat Starfire is, he'd stop screwin around and come up with somethin to actually beat her.
Meanwhile in character Starfire never fought very smart. She'd bumrush, a lot, which usually worked because of the power differences between her and her opponents, however when it came to tactics she usually took her directions from Robin. She also absolutely held back because she didn't want to outright kill someone. Her raw power absolutely outclasses Tony, but I'd give him a majority of fights in round 1 for the times he'd use his brain to actually win.
Round 2 though its an absolute slaughter. Starfire wouldn't be holding back anymore and would be able to simply cave Tony's chest in, through his armor. The only chance Tony has is a full on Unibeam, but if it misses he's even more screwed than he was before because of the downtime after using it.
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