Spider-Man (PS4) vs Captain America & Bucky (MCU)

Spider-Man gets his gadgets.

RD2: Add Falcon but Spidey also gets to pick his suit too.

Bonus: Cap gets Mjolnir

Win by death/KO/incapacitation

All in character

Spidey stomps

Cap solos bonus

Spider-Man stomps them with ease even without comic feats. Just the original game's feats have him as insanely more powerful than Captain America and Bucky's combined strength.

Spidey blitzes the first round. He scales to his 616 counterpart via a tie in comic.

Whether or not 616 Spidey can beat Mjonir Cap is debatable.

Depends. If Bucky has a second rifle, he solos.

Spider-Man stomps

Both rounds are one-sided