I'd say he can clear or stops at Superman.
Fury's scenario is almost too easy - he's watching people get dusted and is completely distracted. Easy shot for Frank.
Wanda just won't see him coming, like Fury. She did contain an explosion, but that was when she was close enough and fully aware of her surroundings, unlike this situation.
Tobey has never properly reacted to gunfire or anything nearly as fast, a surprise sniper shot should land.
Wonder Woman has shown to get tagged by normal humans if she's distracted, so instead of the stock of a gun hitting her in the head, it'll be a bullet passing right through.
Superman's hard to tell, although I'd count on him just not expecting someone to choose to shoot him during the middle of the day. His senses might be able to alert him, but with so much sound coming from the busy street he's walking past, it's dubious to say he could react to it. Indecisive on this one.
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