MCU Daisy Johnson vs Captain America (Read OP)

Daisy Johnson and Steve Rogers face off in a random encounter with the opponents having no knowledge of each other.

Unarmed combat.

Daisy has the Centipede serum but she's not allowed to quake.

Morals off.

Win by KO/Incapacitation/Death.

PS: I'll update the OP with pictures when I get back on my computer :)

We don't really know what the centipede serum did to her physicals

If we assume the serum grants Daisy the same stats as Centipede soldiers, Mike, or Garrett then she stomps.

Scaling from other Centipede soldiers, she'll win comfortably. She's already more skilled. Centipede serum makes her physically superior as well.

Plus it has healing properties from Jiaying's DNA so she'd be pretty op