I'd say it's probably somewhat sticky, but not enough for it to be completely impossible for Luffy to escape. I mean, have you ever actually held Gel? It's not that sticky, and I'm sure with Luffy's rubber body it would be even less sticky.
Well the only common gel I know is toothpaste and I can assure you if that amount of toothpaste was wrapped around me as it was around Luffy, I wouldn't be able to escape it without carrying a significant amount with me.
And Slime is quite sticky, we have instances of it climbing and crossing mountains using its sticky nature to cling to the surface.
Don't forget gels have a liquid component as well (in fact Slime has also been described as a liquid on panel), its not just sticking, but also wetting.
I agree, Slime CAN be very sticky, but for the most part it isn't too sticky.
For the liquid part, the only pieces that would stick on his clothes/skin would be those that actually come into contact with it.
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