Itachi won't make it out alive. Itachi might have a slim chance here if he traps the most dangerous person on the field with a genjustu and then uses Susanoo to defend himself until he can figure out a game plan. The most dangerous person is whoever has the gauntlet. That would normally be Thanos. But even then his chances are extremely slim. He has too many variable to deal with. Several enemies can fly. His biggest problems would be Thanos, Marvel, Scarlet, Thor, Hulk, Ironman, Starlord, and Dr.Strange.
Marvel, Ironman, Scarlet, Thor, and Starlord are all airborne capable opponents. Itachi doesn't have the luxury of ignoring them for too long since they can blast him while hovering in the sky. Dr.Strange and Scarlet can dispel Itachi's genjutsu over anyone he uses it on. Hulk, Antman, Thor, AND Thanos are heavy hitters. They will tax the hell out of Itachi's sussanoo. Amaterasu would probably be his best choice offensively. But that would still tax him heavily and he'll have to repeatedly tie down a Hulk. Something that is virtually impossible to do why trying to fend off so many airborne opponents.
If he WAS to make it a fight, he would have to grab hold of the infinity stones almost asap in order to increase his survival rate. Which goes back to what i was saying earlier about targeting the most dangerous person. It could be Spidey, Black Panther, Captain Marvel, or even Thanos since they all held the gauntlet. Otherwise this many enemies will overwhelm him.
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