I think it would. I haven't seen Quantico this past season, but the terrorist storyline and the subplot about the mole reminded me of 24.
It could work as a crossover. Something like Prison Break or Person of Interest would be cool too.
Firearms could go either way. Jack probably has a slight advantage, but it depends on what equipment they have access to.
I think much of that has to do with how Quantico is meant to be a fairly down-to-Earth/realistic show. I don't disagree with your reasoning, I just think that's the main reason why; Quantico characters are meant to be more realistic than stuff that's intended more as an action movie or thriller series.
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