Dylan Brock appears in 27 issues.
Ann Weying was the ex-wife of Eddie Brock, and briefly wore the Venom symbiote.
Eddie Brock bonded to the alien symbiote after it was discarded by Spider-Man, becoming the first Venom. Brock was later Anti-Venom, but the symbiote was lost during Spider-Island. Brock has also been forcibly bonded to the Toxin symbiote by the Crime Master, but has reluctantly given it up to stop Carnage. He has recently been rebonded with Venom.
Child symbiote that originally bonded with the Scorpion. Venom and Eddie Brock took the leave the young symbiote with Alchemax with the understanding that he would be studied in a non-invasive fashion.
The Venom symbiote bonded with Spider-Man during his adventure in the first "Secret Wars" on the Beyonder's makeshift planet called Battleworld. Initially, he thought the symbiote was just a costume. However upon his discovery that it was sentient, he rejected it. Since then, the symbiote has bonded with several different hosts. It's current host is Eddie Brock.
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