Domino's luck power depends alot on the writer, but here are examples of how it works.
First of all, traditionally she never misses when she shoots because of her luck. And, if she sees someone pull a gun on her, her luck power also goes into effect. This has lead to everything from her dodging the bullet by moving just in the right place to avoid the bullet, to one time in which there was a gun right next to her head which misfired. Another time, she was fighting Deathstrike and blew up the building they were in. Domino knew she would move in just the right way to avoid any harm from the explosion due to her luck, but Deathstrike would not.
As I recall, there was an extreme example of her power where she was facing a Sentinel and needed lightning to strike the Sentinel, and so it did.
However, in recent years, like in Kyle and Yost's X-Force series, there were times in which her luck power didn't work. The reasoning for this hasn't been explored (that I know of) though, because Domino hasn't been a major character much since their X-Force run.
I hope I'm explaining this well though. It's such an odd power, and depends so much on what the writer thinks would be a cool use for her power, that it's hard to explain. But basically things just naturally go her way to help her.
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