Little is know about Bootface's origin other then at one point Batman kicked him in the face while he was using a flamethrower and the boot print became permanent.
Bootface was created by Peter J. Tomasi, Patrick Gleason and Mick Gray for there run on Batman and Robin.
Major Story Arcs
Batman and Robin:Terminus
Bootface has been enlisted into Terminus's army of revenge along with Smush, Scallop, Bat Head and several others that blame the Batman for there current conditions. After the initial meeting, where its revealed that each member had been working for Terminus for some time but never knew it, the army is sent out to spread fear. Their mission is to brand as many people withe the Batman's logo before the sun comes up. This is something that Bootface takes great pleasure in. Then when the Bat Family shows up to stop the group, both Damian and Jason Todd take pleasure in kicking Bootface in the face. After Terminus is defeated it is assumed Bootface, along with the rest of the army is taken away to jail.
Powers and Abilities
Bootface does not seem to possess and super natural powers.