The instance of her shooting fire from her cloak is from an annual, I think, during her White Cloak days where they fought a guy called Muse who invaded their dreams in order to kill them. They all manage to beat him back out of their dreams using various skills and techniques they use in their waking hour, so it is by some of us believed Raven could do the same trick in the waking world.
The electricity blasts on the other hand are from Winnick's Titans, first time since she was reborn that Raven went completely demonic, where she used it as her primary attack against her brothers and the Titans.
Granted, Raven is in a bit of a grey zone when it comes to this. As she is a DC half-demon, we can assume most of her powers are magically connected in one way or another, but for the most part she appears to be primarily psionic-powered because of how she employs them (which was the challenge Len Wein gave Wolfman when he asked him to come up with a new type of mystic that didn't resemble Phantom Stranger or Dr. Strange).
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