Iron Man appears in 329 issues in this volume.
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Issue #1
Alone Against A.I.M.!: The Origin of Iron Man
May 1968
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Issue #2
The Day Of The Demolisher!
June 1, 1968
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Issue #3
My Friend, My Foe...The Freak!
July 1968
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Issue #4
Unconquered Is the Unicorn!
August 1, 1968
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Issue #5
Frenzy in a Far-Flung Future!
September 1, 1968
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Issue #6
Vengeance... Cries The Crusher!
October 1, 1968
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Issue #7
The Maggia Strikes
November 1, 1968
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Issue #8
A Duel Must End!
December 1, 1968
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Issue #9
...There Lives A Green Goliath
January 1, 1969
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Issue #10
Once More...The Mandarin!
February 1, 1969
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Issue #11
Unmasked!
March 1, 1969
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Issue #12
The Coming of the Controller
April 1, 1969
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Issue #13
Captives of the Controller
May 1, 1969
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Issue #14
The Night Phantom Walks!
June 1, 1969
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Issue #15
Said the Unicorn to the Ghost---!
July 1, 1969
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Issue #16
Of Beasts and Men!
August 1, 1969
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Issue #17
The Beginning of the End
September 1969
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Issue #18
Even Heroes Die
October 1, 1969
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Issue #19
What Price Life?!
November 1, 1969
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Issue #20
Who Serves Lucifer?
December 1, 1969
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Issue #21
The Replacement
January 1, 1970
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Issue #22
From this Conflict...DEATH!
February 1, 1970
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Issue #23
The Man Who Killed Tony Stark!
March 1970
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Issue #24
My Son...The Minotaur!
April 1, 1970
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Issue #25
This Doomed Land - This Dying Sea!
May 1, 1970
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Issue #26
Duel in a Dark Dimension!
June 1, 1970
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Issue #27
The Fury of the Firebrand!
July 1, 1970
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Issue #28
The Controller Lives!
August 1, 1970
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Issue #29
Save the People - - Save the Country!
September 1, 1970
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Issue #30
The Menace of the Monster-Master!!
October 1, 1970
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Issue #31
Anything - - For The Cause!
November 1, 1970
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Issue #32
Beware - - The Mechanoid!
December 1, 1970
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Issue #33
Destroy Stark Industries
January 1, 1971
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Issue #34
Crisis and Calamity
February 1, 1971
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Issue #35
Revenge
March 1, 1971
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Issue #36
...Among Men Stalks the Ramrod!
April 1, 1971
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Issue #37
In This Hour of Earthdoom!
May 1, 1971
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Issue #38
When Calls Jonah..!
June 1, 1971
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Issue #39
A Twist of Memory -- A Turn of Mind!
July 1, 1971
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Issue #40
Night Walk!
August 1, 1971
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