In that case i'll say Zoro via win by KO. while wolverine can't be killed due to zoro's inability to cut Adamantium (which is equivalent to diamonds) it isn't impossible to knock him out. any impact strong enough can stun and knock him out through shock.
Zoro is stronger than spider man (he's lifted two story homes before so he's definitely 100 ton+ in terms of lifting strength) on another occasion he shoulder pressed around 25 ton dumb bells casually so Winning via knock out wouldn't be hard.
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