Hidan is never shown to be fast, just extremely agile. He was able to dodge every attack Asuma made against him until Shikamaru locked him down. Hidan is also extremely durable and nearly inexhaustible, but it's shown that his body is still controlled by his head, and if that's removed he'd basically powerless, which is why he focuses so much on defense. He'll survive anything (he's a True Immortal), but he won't be much good if he's torn to pieces.
Wade Wilson is not all that fast and there are characters much more agile than he is. He doesn't really avoid attacks because he doesn't need to, since his healing factor is so ridiculously awesome. So much so that he can just stick a dismembered limb back to its stump and it'll reattach. He's even able to control his body if his head is removed, somehow. Something Hidan can't do.
Hidan's entire offense is based on drawing blood through a shallow cut so he can perform his Jashin ritual.
Wade's offense is based on killing you. Quickly.
Thus, the fight would probably proceed as thus:
- Hidan attacks Wade, who doesn't avoid since he's too busy commenting on the massive 3-bladed scythe. Something about overcompensating or something. Hidan draws blood, to his overly zealous glee.
- Hidan begins ritual, which Wade doesn't interrupt out of curiousity.
- Ritual destroys Wade's heart, which startles him a bit, but ultimately doesn't kill him, obviously.
- Hidan grows infuriated and begins stabbing himself all over, which Wade experiences too, but doesn't die from.
- Hidan becomes enraged and charges a fully healed Wade. Melee battle ensues, but Hidan is less cautious and growing even more enraged by Wade's chatterbox commenting and eventually loses his head.
- Wade reenacts Lollipop Chainsaw (while wearing a cheerleader outfit?) by carrying Hidan's head around with him.
- The end.
But that's my opinion.
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