Actually Alan Scott > Ion Kyle Rayner (or at least Sodam Yat). Ion have not show reality warping yet, though theoretically can. Alan Scott have hanged with Parallax, which have better feats than Ion.
I think you are comparing 2 different ION's here, there is one version of Kyle merged with the Ion Entity from Green Lantern central battery, where he has that star spangle costume, he was pretty powerful but like you said hasnt really shown reality warping or anything impressive.
Then we have a different version of ION, from the story Hand Of God, which has well nothing to do with Ion Entity, but rather he was merged with exact same energies as Zero Hour Parallax (Green Lantern Central Battery + Left Over Energies from COIE). Even this version doesnt have a lot of feats, but there is a long fleshed out conversation between Kyle and Hal Jordan as Spectre, which kind of shows that Kyle was capable of doing exactly what Hal Jordan did, destroy and recreate all reality, and Spectre (as Hal ) would not have been able to stop him.
I would put HOG Ion or Zero Hour Parallax, 2 different person, 2 different persona, but identical power source, above Starheart.
As per the thread, i am backing Starheart , because well reality warping, time manipulation, ability to take control of people body (not sure if there is really anything preventing Alan Scott from taking over the guardian and making them fight GL corps themselves), ability to make construct with Superman human power, identical to existing Superman etc, as very hard to counter.
If however the Guardians can overcome Starheart taking them over, Guardian together, as an assemblage should be able to stop Alan Scott, he wasnt shown to be any more powerful than say SCW Anti-Monitor.
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